Matte Crystalline Glaze: Focus - Mondre & Manz 4067 Frit
The first time I saw a matte crystalline glaze was on a piece by Hein Severijns. Both the bottle and the glaze recipe were spotlighted in the book, “Smashing Glazes”, by Professor Susan Peterson. Neither the recipe, nor the corresponding firing schedule looked easy.
It was only a short time later, when John Tilton’s crystalline mattes caught my eye.
Tilton has told me many times how troublesome these glazes are to produce (refer to the relevant Clay Times Article), but those that come out well are extraordinary.
In 2006, while preparing for the Peter Ilsley Workshop, Ilsley referred to the glaze developed by Peter Fröhlich. The glaze recipe is listed in Ilsley’s book, “Macro-Crystalline Glazes”:
Matt - 1260°C
Frit 4067 : 77
Feldspar Potash: 21
Zinc Oxide: 16
Lead bisilicate: 11
Flint: 7
Rutile: 8
The 4067 frit is manufactured by Mondre & Manz in Germany. It is only one of the frits that host Kris Friedrich had shipped in for the Ilsley Workshop.
At the workshop, John Tilton, Marsha Silverman, and Mark & Scott Winner focused on developing Fröhlich’s recipe, with good success.
The chemical formula for MM 4067 is:
K2O: 4.60
ZnO: 12.00
BaO: 37.80
Pb2O3: 11.00
Al2O3: 5.00
SiO2: 29.60
Although MM frit 4067 is not available in North America, a number of people are still experimenting, either by using the frit directly or by substitution. Chris Cantello has discussed some ideas on this site (see the comments section at the bottom of the Ilsley workshop page).
Andreas Widhalm created a frit replacement through a computer program he developed, employing the Seger Method:
Potash Feldspar: 24.411
Lead Mono-silicate: 12.649
Zinc Oxide (Calcined): 10.917
Barium Carbonate: 43.947
325 mesh Silica: 8.077
Bill Campbell has been firing some gorgeous matte crystallines. It employs neither the MM 4067, nor the additional Lead component called for in Fröhlich’s matte recipe.
As for myself, I am working with a glaze (and a process) that doesn’t rely on lead or the German frit as well.
This matte/satin-matte effect is achieved by a combination of chemically altering the base glaze, putting it through a standard crystalline firing, and then re-firing it to just below it’s melting point. It’s tricky, as firing it even a bit hotter than necessary will cause the glaze to soften too much and produce a blistered surface. Glazes fired in this way without the chemical modifications may provide a similar effect, but the loss rate is higher, due to an even smaller heatwork window. A piece must often be put through several firings before it yields the right surface –but once it blisters, it’s ruined.
Needless to say, at this point I’m doing very few of these.

